ASTM D6346-17(2025) 通过家用危险废物方案收集分类和包装材料的标准指南

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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the

Development of International Standards,Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade(TBT)Committee.

Designation:D6346-17(Reapproved 2025)

INTERNATIONAL

Standard Guide for

Accepting,Segregating,and Packaging Materials Collected

Through Household Hazardous Waste Programs

This standard is issued under the fixed designation D6346;the number immediately following the designation indicates the year of

original adoption or,in the case of revision,the year of last revision.A number in parentheses indicates the year of last reapproval.A

superscript epsilon(ε)indicates an editorial change since the last revision or reapproval.

1.Scope

1.1 This guide covers Household Hazardous Waste(HHW)

programs for accepting,segregating,and packaging materials

collected through HHW programs to minimize the risk asso-

ciated with managing these materials and to identify applicable

regulations.This guide does not address storing,vehicle

loading,or transporting collected and packaged materials.This

guide does not attempt to define the hazardous nature of

materials.

1.2 Certain existing local,state,and federal regulations

apply to HHW program operations.This guide does not replace

these existing regulations,and is not intended to be used as the

basis for regulations for HHW programs.This guide does not

reference all applicable applications,since applicable regula-

tions will vary.HHW programs should research all applicable

regulations before establishing a materials collection program.

1.3 This standard does not purport to address all of the

safety concerns,if any,associated with its use.It is the

responsibility of the user of this standard to establish appro-

priate safety,health,and environmental practices and deter-

mine the applicability of regulatory limitations prior to use.

1.4 This international standard was developed in accor-

dance with internationally recognized principles on standard-

ization established in the Decision on Principles for the

Development of International Standards,Guides and Recom-

mendations issued by the World Trade Organization Technical

Barriers to Trade(TBT)Committee.

2.Referenced Documents

2.1 ASTM Standards:²

D5681 Terminology for Waste and Waste Management

!This guide is under the jurisdiction of ASTM Committee D34 on Waste

Management and is the direct responsibility of Subcommittee D34.03 on Treatment,

Recovery and Reuse.

Current edition approved Nov.1,2025.Published November 2025.Originally

approved in 1998.Last previous edition approved in 2017 as D6346-17.DOI:

10.1520/D6346-17R25.

²For referenced ASTM standards,visit the ASTM website,www.astm.org,or

contact ASTM Customer Service at www.astm.org/contact.For Annual Book of

ASTM Standards volume information,refer to the standard's Document Summary

page on the ASTM website.

2.2 Code of Federal Regulations(CFR):³

CFR Title 49 Parts 100-185 Transportation

CFR Title 40 Part 261.5 Protection of Environment

3.Terminology

3.1 Definitions:

3.1.1 For definitions of general waste management terms

used in this standard,refer to Terminology D5681.

3.1.2 bulking—the act of emptying multiple containers of

compatible materials and mixing those materials together in a

single package unit destined for shipment.This would also

include material placed in storage tanks to be packaged for

shipment at a later date,or pumped into a bulk tank truck for

shipment.

3.1.3 consolidation—the act of combining two or more

materials to make a single package unit.Common types of

consolidation packaging used by HHW programs include:

bulking,lab packaging,and composite packaging.

3.1.4 package or outside package—a package plus its con-

tents.

3.1.5 packaging—a receptacle and any other components or

materials(drums,boxes,liners,absorbents,etc.)necessary for

the receptacle to perform its containment function in confor-

mance with the minimum packing requirements of 40 CFR

171,172,173.

4.Significance and Use

4.1 This guide is intended to provide general guidance to

HHW programs for accepting and segregating materials,se-

lecting a management method,and packaging materials col-

lected by HHW programs.

5.Procedure

5.1 Accepting Materials—HHW programs should establish

a list of materials that will be accepted at its facilities or event

collections.The list should be distributed to the public prior to

the facility opening or event collection.Types of materials

commonly collected by HHW programs include:

³Available from U.S.Government Printing Office,Superintendent of

Documents,732 N.Capitol St.,NW,Washington,DC 20401-0001,http://

www.access.gpo.gov.

D6346-17(2025)

5.1.1 Materials that exhibit a hazardous characteristic,as

defined in 40 CFR 261.5,such as ignitability,toxicity,

corrosivity,oxidizer,reactivity,or are a listed hazardous waste;

5.1.2 Materials prohibited from local municipal waste man-

agement systems;and

5.1.3 Materials collected to provide a convenience or public

service to a community.

5.2 Personnel Training—HHW programs will need to es-

tablish traffic flow,vehicle unloading,and safety procedures.

All personnel involved with material acceptance should receive

training in material identification,proper lifting procedures,

safety,and personal protective equipment.

5.3 Leaking Containers—Leaking containers should be re-

packaged immediately into a container that is compatible with

the material in the container.

5.4 Unlabeled Containers—Unlabeled containers should be

segregated from other wastes.The individual who brought the

container should be interviewed to assist in identification.Any

further categorization and identification of the material should

be completed as soon as possible.A hazardous materials

contractor or trained staff could perform tests to identify the

materials.

5.5 Segregating Materials—As the materials are collected

they should be segregated into general categories based on

DOT incompatibility and packaging regulations.

5.5.1 Commonly Collected Materials—DOT classifies ma-

terials generated from households as a consumer commodity,

which exempts them from DOT regulations.The materials

listed below are subcategories of DOT classes and are not

intended to be all inclusive,but a guide to the most common

materials collected by HHW programs.

Oil-Based Paint Water-Based (Latex)Paint/Sealer

Fuels Antifreeze

Corrosive Acids Corrosive Bases

Cyanides Dioxins

Pesticide Liquids(including herbicides)Pesticide Solids(including herbicides)

Flammables and Chlorinated Products Organic Peroxides

Oxidizers

Arsenic/Heavy Metals

PCB-Containing Devices

Compressed Gas Cylinders

Batteries

Reactive Solids

Mercury Compounds

Motor Oil

Aerosols

Fluorescent and HID Lamps

5.5.1.1 Once a material is collected by a HHW program,it

should be handled in an appropriate manner based on whether

it exhibits a hazardous characteristic.Amaterial that exhibits a

hazardous characteristic or meets the definition of a listed

hazardous waste or material should be transported in accor-

dance with DOT regulations for its specific hazard class.

5.5.2 Materials Requiring Special Handling—The materials

listed below require special handling.HHW programs do not

typically promote accepting these materials through their

programs.However,these materials are brought to collection

facilities and it is wise to be prepared to refer people to the

appropriate local management option or to handle the materials

at the facility.Management options are suggested below for

these materials.The handling of these materials should be

addressed in the site safety and emergency response plan for

the facility.

5.5.2.1 Explosives,Ammunition or Fireworks—Contact lo-

cal law enforcement or bomb squad.

5.5.2.2 Radioactive Materials—Refer to appropriate man-

agement option or contact Nuclear Regulatory Commission.

5.5.2.3 Friable Asbestos—Refer to local management facil-

ity or accept in accordance with local,state,and federal

regulations.

5.5.2.4 Medical/Infectious Materials—Refer to local man-

agement option or accept in accordance with local,state,and

federal regulations.

5.5.2.5 Consumer Electronics and Appliances—These items

may have hazardous components and should be handled by a

local handler,or may be managed through the HHW program.

5.5.3 Incompatibility and Segregation of Materials—

Incompatible materials,when mixed,generate chemical reac-

tions which may result in serious safety and health concerns.

These include toxic gas generation,heat generation,flammable

gas generation,fire,explosion,or polymerization of materials.

Containers of incompatible materials should be adequately

separated using bins,drums,dikes,walls,or other devices,

such that mixing of incompatible materials is prevented in the

event of a spill,or a break or leak in a container.

5.5.3.1 Material and container segregation procedures

should be established before waste is accepted.Procedures

should be based on the type of materials accepted,facility

design and facility operation.Personnel responsible for segre-

gating wastes should be properly trained in chemical manage-

ment and safety.The following list gives only general guidance

on incompatible categories of materials.

Always Segregate: From:

Acids Bases,cyanides

Oxidizers Flammables

Cyanides Acids,oxidizers

5.6 Selecting a Management Method for Collected

Materials—Prior to consolidating materials,the ultimate man-

agement method for the material should be considered.The

management method selected may affect how the materials will

be packaged.Common management practices include:reuse,

recycling,energy recovery,on-site treatment,incineration,land

disposal,and waste water treatment.

5.6.1 When selecting the most appropriate material manage-

ment method,HHW programs should consider several factors,

including:

5.6.1.1 Compliance with permitting requirements and local,

state,and federal regulations (especially when performing

on-site treatment of materials);

5.6.1.2 Operational or structural limitations at facilities or

event collections (that is,no product reuse available on-site,no

connection to sewer treatment facility,limited space);

5.6.1.3 Personnel training and expertise;

5.6.1.4 Consideration of a materials management hierarchy

that favors reuse,recycling,and energy or material recovery

over incineration or land disposal;

5.6.1.5 Compliance with DOT hazardous waste regulations

(49 CFR Parts 100-185);

5.6.1.6 Cost;

5.6.1.7 Potential liability related to each management

method;and

5.6.1.8 Contractual or contractor restrictions or preferences.

D6346-17(2025)

5.7 Packaging Collected Materials—Collected materials

need to be packaged or handled according to facility standards

and local,state,and federal regulations.Materials management

contractors may also have specific packaging protocol that

must be followed so that they can properly and efficiently

process materials at their facilities.Unlabeled containers or

questionable materials should not be packaged until they are

properly identified.

5.7.1 On-Site Management Options and Packaging:

5.7.1.1 Reuse—Usable materials in original containers that

are offered to local residents or organizations during an event

collection or at a permanent site should be left in their original

containers.This allows users to reference original label infor-

mation for proper use,and preserves the manufacturers'

product liability.

5.7.1.2 Paints or other materials may be bulked into larger

containers.However,the HHW program may be considered to

be engaging in a manufacturing operation when this is done.

5.7.1.3 Recycle—If materials are to be recycled on-site,they

do not need to be packaged according to DOT protocol.Some

items may be bulked or packaged into larger containers

according to facility protocol and local regulations.

5.7.1.4 Treatment or Disposal On-Site—Many water-based

cleaners and nonhazardous liquid materials may be sewered if

the site is connected to the local wastewater treatment plant and

has permission from the plant to do so.Some acids and bases

may also be neutralized and sewered on-site in accordance with

local or state regulations.Materials do not need to be packaged

according to DOT protocol if treated or sewered on-site.A site

safety or operational plan should be developed to describe in

detail the process used to treat or dispose of wastes on-site.

5.7.1.5 Nonhazardous solids may be disposed of using the

facility's solid waste management service and container

5.7.1.6 Energy Recovery—If an energy recovery option is

available on-site(that is,used oil furnace,municipal solid

waste incinerator),the material should be handled and pack-

aged according to the facility's standard protocol and all

applicable regulations.

5.7.2 Off-Site Management and Packaging—Materials that

will be shipped off-site for further management at recycling,

energy recovery,incineration,or land disposal facilities should

conform to DOT regulations.This includes the packaging of

the materials and selecting a receiving facility that conforms to

local regulations governing the management of hazardous

materials.Therefore,it makes sense to initially package all

materials which will leave the site in accordance with DOT

regulations.These packaging methods are fully detailed in

DOT regulations,49 CFR Parts 171-178.These regulations

describe the specific container types,packaging procedures,

and container labeling required for each sub-category of

material identified in 5.5.1.HHW programs that intend to

package their own materials need to become familiar with

DOT regulations in order to properly package materials.

Programs may also hire trained contractors to perform pack-

aging on-site.

6.Keywords

6.1 compatibility;household hazardous waste;incompat-

ibility;packaging;segregation

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in this standard.Users of this standard are expressly advised that determination of the validity of any such patent rights,and the risk

of infringement of such rights,are entirely their own responsibility.

This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and

if ot revised,either reapproved or withdrawn. Your comments are invited either for revision of this standard or for aditional standards

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1ThisinternationalstandardwasdevelopedinaccordancewithinternationallyrecognizedprinciplesonstandardizationestablishedintheDecisiononPrinciplesfortheDevelopmentofInternationalStandards,GuidesandRecommendationsissuedbytheWorldTradeOrganizationTechnicalBarrierstoTrade(TBT)Committee.Designation:D6346-17...

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